| 1 | 2002 | Curt Schilling | 23 | 7 | 0 | 36 | 35 | 259.1 | 10.97 | 1.15 | 1.01 | .297 | 74.5% | 41.8% | 12.3% | 3.23 | 2.40 | 2.20 | 9.3 | 9.58 |
| 2 | 2001 | Curt Schilling | 22 | 6 | 0 | 35 | 35 | 256.2 | 10.27 | 1.37 | 1.30 | .307 | 84.8% | | | 2.98 | 3.11 | | 7.2 | 7.51 |
| 3 | 2004 | Randy Johnson | 16 | 14 | 0 | 35 | 35 | 245.2 | 10.62 | 1.61 | 0.66 | .264 | 69.5% | 43.1% | 8.0% | 2.60 | 2.30 | 2.68 | 9.6 | 6.59 |
| 4 | 2003 | Curt Schilling | 8 | 9 | 0 | 24 | 24 | 168.0 | 10.39 | 1.71 | 0.91 | .297 | 78.0% | 41.5% | 10.8% | 2.95 | 2.66 | 2.71 | 5.6 | 6.06 |
| 5 | 2009 | Dan Haren | 14 | 10 | 0 | 33 | 33 | 229.1 | 8.75 | 1.49 | 1.06 | .267 | 77.0% | 42.9% | 11.7% | 3.14 | 3.23 | 3.02 | 5.3 | 5.87 |
| 6 | 2001 | Randy Johnson | 21 | 6 | 0 | 35 | 34 | 249.2 | 13.41 | 2.56 | 0.68 | .315 | 80.5% | | | 2.49 | 2.13 | | 10.4 | 5.24 |
| 7 | 1999 | Randy Johnson | 17 | 9 | 0 | 35 | 35 | 271.2 | 12.06 | 2.32 | 0.99 | .292 | 82.0% | | | 2.48 | 2.76 | | 9.5 | 5.20 |
| 8 | 2008 | Dan Haren | 16 | 8 | 0 | 33 | 33 | 216.0 | 8.58 | 1.67 | 0.79 | .303 | 73.4% | 44.2% | 8.9% | 3.33 | 3.01 | 3.16 | 6.1 | 5.15 |
| 9 | 2017 | Zack Greinke | 17 | 7 | 0 | 32 | 32 | 202.1 | 9.56 | 2.00 | 1.11 | .285 | 75.3% | 46.8% | 13.4% | 3.20 | 3.31 | 3.34 | 4.9 | 4.78 |
| 10 | 2002 | Randy Johnson | 24 | 5 | 0 | 35 | 35 | 260.0 | 11.56 | 2.46 | 0.90 | .289 | 83.0% | 46.6% | 12.5% | 2.32 | 2.66 | 2.48 | 8.1 | 4.70 |
| 11 | 2000 | Randy Johnson | 19 | 7 | 0 | 35 | 35 | 248.2 | 12.56 | 2.75 | 0.83 | .326 | 77.4% | | | 2.64 | 2.53 | | 9.6 | 4.57 |
| 12 | 2005 | Javier Vazquez | 11 | 15 | 0 | 33 | 33 | 215.2 | 8.01 | 1.92 | 1.46 | .300 | 72.0% | 42.3% | 16.3% | 4.42 | 4.06 | 3.32 | 3.5 | 4.17 |
| 13 | 1998 | Brian Anderson | 12 | 13 | 0 | 32 | 32 | 208.0 | 4.11 | 1.04 | 1.69 | .266 | 72.0% | | | 4.33 | 5.07 | | 1.0 | 3.96 |
| 14 | 2008 | Randy Johnson | 11 | 10 | 0 | 30 | 30 | 184.0 | 8.46 | 2.15 | 1.17 | .301 | 70.9% | 40.2% | 10.8% | 3.91 | 3.76 | 3.66 | 3.6 | 3.93 |
| 15 | 2012 | Wade Miley | 16 | 11 | 0 | 32 | 29 | 194.2 | 6.66 | 1.71 | 0.65 | .293 | 72.0% | 43.3% | 6.9% | 3.33 | 3.15 | 3.75 | 3.9 | 3.89 |
| 16 | 2011 | Ian Kennedy | 21 | 4 | 0 | 33 | 33 | 222.0 | 8.03 | 2.23 | 0.77 | .270 | 79.2% | 38.6% | 7.7% | 2.88 | 3.22 | 3.50 | 4.4 | 3.60 |
| 17 | 2006 | Brandon Webb | 16 | 8 | 0 | 33 | 33 | 235.0 | 6.82 | 1.91 | 0.57 | .287 | 72.1% | 66.3% | 13.2% | 3.10 | 3.18 | 3.03 | 6.5 | 3.56 |
| 18 | 2012 | Ian Kennedy | 15 | 12 | 0 | 33 | 33 | 208.1 | 8.08 | 2.38 | 1.21 | .306 | 74.9% | 37.3% | 10.8% | 4.02 | 4.04 | 4.13 | 2.4 | 3.40 |
| 19 | 2011 | Daniel Hudson | 16 | 12 | 0 | 33 | 33 | 222.0 | 6.85 | 2.03 | 0.69 | .295 | 70.5% | 41.7% | 6.4% | 3.49 | 3.28 | 3.79 | 4.2 | 3.38 |
| 20 | 2013 | Patrick Corbin | 14 | 8 | 0 | 32 | 32 | 208.1 | 7.69 | 2.33 | 0.82 | .283 | 75.9% | 46.7% | 10.1% | 3.41 | 3.43 | 3.48 | 3.3 | 3.30 |
| 21 | 2017 | Robbie Ray | 15 | 5 | 0 | 28 | 28 | 162.0 | 12.11 | 3.94 | 1.28 | .267 | 84.5% | 40.3% | 15.6% | 2.89 | 3.72 | 3.49 | 3.3 | 3.07 |
| 22 | 2016 | Robbie Ray | 8 | 15 | 0 | 32 | 32 | 174.1 | 11.25 | 3.67 | 1.24 | .352 | 68.7% | 45.7% | 15.5% | 4.90 | 3.76 | 3.45 | 3.3 | 3.07 |
| 23 | 2014 | Josh Collmenter | 11 | 9 | 1 | 33 | 28 | 179.1 | 5.77 | 1.96 | 0.90 | .267 | 72.5% | 38.8% | 8.3% | 3.46 | 3.87 | 4.07 | 1.6 | 2.95 |
| 24 | 2017 | Patrick Corbin | 14 | 13 | 0 | 33 | 32 | 189.2 | 8.45 | 2.89 | 1.23 | .326 | 74.3% | 50.4% | 15.3% | 4.03 | 4.08 | 3.89 | 3.0 | 2.92 |
| 25 | 2005 | Brandon Webb | 14 | 12 | 0 | 33 | 33 | 229.0 | 6.76 | 2.32 | 0.83 | .302 | 73.7% | 65.0% | 18.8% | 3.54 | 3.51 | 2.99 | 4.8 | 2.92 |
| 26 | 2008 | Brandon Webb | 22 | 7 | 0 | 34 | 34 | 226.2 | 7.27 | 2.58 | 0.52 | .288 | 71.0% | 64.4% | 9.6% | 3.30 | 3.28 | 3.33 | 5.5 | 2.82 |
| 27 | 2009 | Max Scherzer | 9 | 11 | 0 | 30 | 30 | 170.1 | 9.19 | 3.33 | 1.06 | .308 | 68.7% | 41.8% | 10.4% | 4.12 | 3.87 | 3.82 | 2.7 | 2.76 |
| 28 | 2007 | Brandon Webb | 18 | 10 | 0 | 34 | 34 | 236.1 | 7.39 | 2.74 | 0.46 | .285 | 72.4% | 61.8% | 8.8% | 3.01 | 3.24 | 3.30 | 6.2 | 2.69 |
| 29 | 2000 | Brian Anderson | 11 | 7 | 0 | 33 | 32 | 213.1 | 4.39 | 1.65 | 1.60 | .272 | 77.7% | | | 4.05 | 5.07 | | 2.0 | 2.67 |
| 30 | 1998 | Omar Daal | 8 | 12 | 0 | 33 | 23 | 162.2 | 7.30 | 2.82 | 0.66 | .288 | 76.4% | | | 2.88 | 3.47 | | 3.5 | 2.59 |